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Laptop

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A laptop is a personal computer designed for mobile use and small and light enough to sit on a person's lap while in use.[1] A laptop integrates most of the typical components of a desktop computer, including a display, a keyboard, a pointing device (a touchpad, also known as a trackpad, and/or a pointing stick), speakers, and often including a battery, into a single small and light unit. The rechargeable battery (if present) is charged from an AC adapter and typically stores enough energy to run the laptop for two to three hours in its initial state, depending on the configuration and power management of the computer.

Laptops are usually notebook-shaped with thicknesses between 0.7–1.5 inches (18–38 mm) and dimensions ranging from 10x8 inches (27x22cm, 13" display) to 15x11 inches (39x28cm, 17" display) and up. Modern laptops weigh 3 to 12 pounds (1.4 to 5.4 kg); older laptops were usually heavier. Most laptops are designed in the flip form factor to protect the screen and the keyboard when closed. Modern tablet laptops have a complex joint between the keyboard housing and the display, permitting the display panel to swivel and then lie flat on the keyboard housing.

Laptops were originally considered to be "a small niche market" and were thought suitable mostly for "specialized field applications" such as "the military, the Internal Revenue Service, accountants and sales representatives". But today, there are already more laptops than desktops in businesses, and laptops are becoming obligatory for student use and more popular for general use. In 2008 more laptops than desktops were sold in the US and it has been predicted[who?] that the same milestone will be reached in the worldwide market as soon as late 2009[citation needed].

Contents

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The Epson HX-20

As the personal computer became feasible in the early 1970s, the idea of a portable personal computer followed. A "personal, portable information manipulator" was imagined by Alan Kay at Xerox PARC in 1968[2] and described in his 1972 paper as the "Dynabook".[3]

The IBM SCAMP project (Special Computer APL Machine Portable), was demonstrated in 1973. This prototype was based on the PALM processor (Put All Logic In Microcode).

The IBM 5100, the first commercially available portable computer, appeared in September 1975, and was based on the SCAMP prototype.[4]

As 8-bit CPU machines became widely accepted, the number of portables increased rapidly. The Osborne 1, released in 1981, used the Zilog Z80 and weighed 23.5 pounds (10.7 kg). It had no battery, a 5" CRT screen and dual 5¼" single-density floppy drives. In the same year the first laptop-sized portable computer, the Epson HX-20, was announced.[5] The Epson had a LCD screen, a rechargeable battery and a calculator-size printer in a 1.6 kg (3.5 lb) chassis. Both Tandy/RadioShack and HP also produced portable computers of varying designs during this period.[6][7]

The first laptops using the flip form factor appeared in the early 1980s. The Dulmont Magnum was released in Australia in 1981-2, but was not marketed internationally until 1984-5. The 8150 US$ GRiD Compass 1100, released in 1982, was used at NASA and by the military among others. The Gavilan SC, released in 1983, was the first notebook marketed using the term "laptop".[8] From 1983 onwards, several new input techniques were developed and included in laptops, including the touchpad (Gavilan SC, 1983), the pointing stick (IBM ThinkPad 700, 1992) and handwriting recognition (Linus Write-Top,[9] 1987). Some CPUs were designed specifically for low power use including laptops (Intel i386SL, 1990), and were supported by dynamic power management features (Intel SpeedStep and AMD PowerNow!) in some designs. Displays reached VGA resolution by 1988 (Compaq SLT/286) and 256-color screens by 1993 (PowerBook 165c), progressing quickly to millions of colors and high resolutions. High-capacity hard drives and optical storage (CD-ROM followed by CD-R and CD-RW and eventually by DVD-ROM and the writable varieties) became available in laptops soon after their introduction to the desktops.

[edit] Classification

The general terms "laptop" or "notebook" can be used to refer to a number of classes of small portable computers:[10][11]

By purpose and (approximately) by screen size:

* Desktop replacement – emphasizes performance, is less portable, 15" and larger screen;

* Standard laptop – balances portability and features, 13-15" screen;

* Subnotebook – emphasizes portability, has fewer features, 12" or smaller screen.

By features:

* Budget – a cheap, lower-performance standard-sized laptop;

* Tablet PC – Has a touch-screen interface, may or may not have a keyboard;

* Netbook – A budget subnotebook suited to Internet surfing and basic office applications. Usually has a 9" or 10" screen.

* Gaming laptop - A larger laptop with a powerful graphics card for playing graphics-intensive computer games.

* Rugged – Engineered to operate in tough conditions (strong vibrations, extreme temperatures, wet and dusty environments).

[edit] Desktop replacement

Dell XPS M140 Laptop.

Main article: Desktop replacement computer

A desktop replacement computer is a laptop that provides most of the capabilities of a desktop computer, with a similar level of performance. Desktop replacements are usually larger and heavier than standard laptops. They contain more powerful components and have a 15" or larger display.[11] Because of their bulk, they are not as portable as other laptops and their operation time on batteries is typically shorter; instead, they are meant to be used as a more compact, easier to carry alternative to a desktop computer.[11]

Some laptops in this class use a limited range of desktop components to provide better performance for the same price at the expense of battery life; in a few of those models, there is no battery at all and the laptop can only be used when plugged in. These are sometimes called desknotes, a portmanteau of the words "desktop" and "notebook," though the term can also be applied to desktop replacement computers in general.[12]

In the early 2000s, desktops were more powerful, easier to upgrade, and much cheaper in comparison with laptops. But in the last few years, the advantages have drastically changed or shrunk since the performance of laptops has markedly increased.[13] In the second half of 2008, laptops have finally outsold desktops for the first time ever. In the U.S., the PC shipment declined 10 percent in the fourth quarter of 2008. In Asia, the worst PC shipment growth went up 1.8 percent over the same quarter the previous year since PC statistics research started.[14]

The names "Media Center Laptops" and "Gaming Laptops" are also used to describe specialized members of this class of notebooks.[10]

[edit] Subnotebook

Sony VAIO P series subnotebook.

Main article: Subnotebook

A subnotebook, also called an ultraportable by some vendors, is a laptop designed and marketed with an emphasis on portability (small size, low weight and longer battery life) that retains the performance of a standard notebook.[15] Subnotebooks are usually smaller and lighter than standard laptops, weighing between 0.8 and 2 kg (2 to 5 pounds);[10] the battery life can exceed 10 hours[16] when a large battery or an additional battery pack is installed.

To achieve the size and weight reductions, ultraportables use high resolution 13" and smaller screens (down to 6.4"), have relatively few ports, employ expensive components designed for minimal size and best power efficiency, and utilize advanced materials and construction methods. Some subnotebooks achieve a further portability improvement by omitting an optical/removable media drive; in this case they may be paired with a docking station that contains the drive and optionally more ports or an additional battery.

The term "subnotebook" is usually reserved to laptops that run general-purpose desktop operating systems such as Windows, Linux or Mac OS X, rather than specialized software such as Windows CE, Palm OS or Internet Tablet OS.

[edit] Netbook

Main article: Netbook

Netbooks are laptops that are light-weight, economical, energy-efficient and especially suited for wireless communication and Internet access.[17][18] Hence the name netbook (as "the device excels in web-based computing performance")[19] rather than notebook which pertains to size.[20]

With primary focus given to web browsing and e-mailing, netbooks "rely heavily on the Internet for remote access to web-based applications"[19] and are targeted increasingly at cloud computing users who rely on servers and require a less powerful client computer.[21] While the devices range in size from below 5 inches[22] to over 12,[23] most are between 7 and 11 inches and weigh between 0.9 - 1.4 kg (2-3 pounds).[19]

Netbooks normally use light-weight operating systems such Linux and Windows XP.

Because they're very portable, Netbooks have a few disadvantages. Because the netbooks are thin, the first such products introduced to the market had their primary internal storage in the form of solid-state drives and not hard disks, which are essential to installing very many programs. Hard disk drive technology and form factors have since been adapted to fit into netbooks.

Given their size and use of more rudimentary components compared to notebooks and subnotebooks, netbooks also generally have a smaller-capacity hard drive, slower CPU, and a lower-profile RAM capacity.[24]

Recently, Google has announced to be developing an own operating system called Chrome for this market.

The big breakthrough for netbook computers did not happen until the weight, diagonal form-factor and price combination of <>

[edit] Rugged laptop

Main article: Rugged computer

A Panasonic Toughbook.

A rugged (or ruggedized) laptop is designed to reliably operate in harsh usage conditions such as strong vibrations, extreme temperatures, and wet or dusty environments. Rugged laptops are usually designed from scratch, rather than adapted from regular consumer laptop models. Rugged notebooks are bulkier, heavier, and much more expensive than regular laptops,[25] and thus are seldom seen in regular consumer use.

The design features found in rugged laptops include rubber sheeting under the keyboard keys, sealed port and connector covers, passive cooling, superbright displays easily readable in daylight, cases and frames made of magnesium alloys[26] that are much stronger than plastic found in commercial laptops, and solid-state storage devices or hard disc drives that are shock mounted to withstand constant vibrations. Rugged laptops are commonly used by public safety services (police, fire and medical emergency), military, utilities, field service technicians, construction, mining and oil drilling personnel. Rugged laptops are usually sold to organizations, rather than individuals, and are rarely marketed via retail channels.

[edit] Components

Main article: Computer hardware

Miniaturization: a comparison of a desktop computer motherboard (ATX form factor) to a motherboard from a 13" laptop (2008 unibody Macbook)

Inner view of a Sony Vaio laptop

The basic components of laptops are similar in function to their desktop counterparts, but are miniaturized, adapted to mobile use, and designed for low power consumption. Because of the additional requirements, laptop components are usually of inferior performance compared to similarly priced desktop parts. Furthermore, the design bounds on power, size, and cooling of laptops limit the maximum performance of laptop parts compared to that of desktop components.[27]

The following list summarizes the differences and distinguishing features of laptop components in comparison to desktop personal computer parts:

* Motherboard – Laptop motherboards are highly make and model specific, and do not conform to a desktop form factor. Unlike a desktop board that usually has several slots for expansion cards (3 to 7 are common), a board for a small, highly integrated laptop may have no expansion slots at all, with all the functionality implemented on the motherboard itself; the only expansion possible in this case is via an external port such as USB. Other boards may have one or more standard, such as ExpressCard, or proprietary expansion slots. Several other functions (storage controllers, networking, sound card and external ports) are implemented on the motherboard.[28]

* Central processing unit (CPU) – Laptop CPUs have advanced power-saving features and produce less heat than desktop processors, but are not as powerful.[29] There is a wide range of CPUs designed for laptops available from Intel (Pentium M, Celeron M, Intel Core and Core 2 Duo), AMD (Athlon, Turion 64, and Sempron), VIA Technologies, Transmeta and others. On the non-x86 architectures, Motorola and IBM produced the chips for the former PowerPC-based Apple laptops (iBook and PowerBook). Some laptops have removable CPUs, although support by the motherboard may be restricted to the specific models.[30] In other laptops the CPU is soldered on the motherboard and is non-replaceable.

A SODIMM memory module.

* Memory (RAM) – SO-DIMM memory modules that are usually found in laptops are about half the size of desktop DIMMs.[28] They may be accessible from the bottom of the laptop for ease of upgrading, or placed in locations not intended for user replacement such as between the keyboard and the motherboard. Currently, most midrange laptops are factory equipped with 3-4 GB of DDR2 RAM, while some higher end notebooks feature up to 8 GB of DDR3 memory. Netbooks however, are commonly equipped with only 1 GB of RAM to keep manufacturing costs low.

* Expansion cards – A PC Card (formerly PCMCIA) or ExpressCard bay for expansion cards is often present on laptops to allow adding and removing functionality, even when the laptop is powered on. Some subsystems (such as Ethernet, Wi-Fi, or a cellular modem) can be implemented as replaceable internal expansion cards, usually accessible under an access cover on the bottom of the laptop. Two popular standards for such cards are MiniPCI and its successor, the PCI Express Mini.[31]

* Power supply – Laptops are typically powered by an internal rechargeable battery that is charged using an external power supply. The power supply can charge the battery and power the laptop simultaneously; when the battery is fully charged, the laptop continues to run on AC power. The charger adds about 400 grams (1 lb) to the overall "transport weight" of the notebook.

* Battery – Current laptops utilize lithium ion batteries, with more recent models using the new lithium polymer technology. These two technologies have largely replaced the older nickel metal-hydride batteries. Typical battery life for standard laptops is two to five hours of light-duty use, but may drop to as little as one hour when doing power-intensive tasks. A battery's performance gradually decreases with time, leading to an eventual replacement in one to three years, depending on the charging and discharging pattern. This large-capacity main battery should not be confused with the much smaller battery nearly all computers use to run the real-time clock and to store the BIOS configuration in the CMOS memory when the computer is off. Lithium-ion batteries do not have a memory effect as older batteries may have. The memory effect happens when one does not use a battery to its fullest extent, then recharges the battery. New innovations in laptops and batteries have seen new possible matchings which can provide up to a full 24 hours of continued operation, assuming average power consumption levels. An example of this is the HP EliteBook 6930p when used with its ultra-capacity battery.

* Video display controller – On standard laptops the video controller is usually integrated into the chipset. This tends to limit the use of laptops for gaming and entertainment, two fields which have constantly escalating hardware demands.[32] Higher-end laptops and desktop replacements in particular often come with dedicated graphics processors on the motherboard or as an internal expansion card. These mobile graphics processors are comparable in performance to mainstream desktop graphic accelerator boards.[33]

* Display – Most modern laptops feature 12 inches (30 cm) or larger color active matrix displays based on a CCFL lamp with resolutions of 1280x800 (16:10) or 1366 x 768 (16:9) pixels and above. Many current models use screens with higher resolution than typical for desktop PCs (for example, the 1440×900 resolution of a 15"). Newer laptops come with LED based screens offering a lesser power consumption and wider viewing angles. Macbook Pro[34] can be found on 19" widescreen desktop monitors.

A size comparison of 3.5" and 2.5" hard disk drives

* Removable media drives – A DVD/CD reader/writer drive is typically standard. CD drives are becoming rare, while Blu-Ray is becoming more common on notebooks.[35] Many ultraportables and netbooks either move the removable media drive into the docking station or exclude it altogether.

* Internal storage – Laptop hard disks are physically smaller—2.5 inches (64 mm) or 1.8 inches (46 mm) —compared to desktop 3.5 inches (89 mm) drives. Some newer laptops (usually ultraportables) employ more expensive, but faster, lighter and power-efficient flash memory-based SSDs instead. Currently, 250 to 500 GB sizes are common for laptop hard disks (64 to 256 GB for SSDs).

* Input – A pointing stick, touchpad or both are used to control the position of the cursor on the screen, and an integrated keyboard is used for typing. An external keyboard and/or mouse may be connected using USB or PS/2 (if present).

* Ports – several USB ports, an external monitor port (VGA or DVI), audio in/out, and an Ethernet network port are found on most laptops. Less common are legacy ports such as a PS/2 keyboard/mouse port, serial port or a parallel port. S-video or composite video ports are more common on consumer-oriented notebooks. HDMI may be found on some higher-end notebooks.

[edit] Docking stations

A docking station is a relatively bulky laptop accessory that contains multiple ports, expansion slots, and bays for fixed or removable drives. A laptop connects and disconnects easily to a docking station, typically through a single large proprietary connector. A port replicator is a simplified docking station that only provides connections from the laptop to input/output ports. Both docking stations and port replicators are intended to be used at a permanent working place (a desk) to offer instant connection to multiple input/output devices and to extend a laptop's capabilities.

Docking stations became a common laptop accessory in the early 1990s. The most common use was in a corporate computing environment where the company had standardized on a common network card and this same card was placed into the docking station. These stations were very large and quite expensive. As the need for additional storage and expansion slots became less critical because of the high integration inside the laptop, port replicators have gained popularity, being a cheaper, often passive device that often simply mates to the connectors on the back of the notebook, or connects via a standardised port such as USB or FireWire.

[edit] Standards

Some laptop components (optical drives, hard drives, memory and internal expansion cards) are relatively standardized, and it is possible to upgrade or replace them in many laptops as long as the new part is of the same type.[31] Depending on the manufacturer and model, a laptop may range from having several standard, easily customizable and upgradeable parts to a proprietary design that cannot be reconfigured at all.

In general, components other than the four categories listed above are not intended to be replaceable, and thus rarely follow a standard. In particular, motherboards, locations of ports, and design and placement of internal components are usually make and model specific. Those parts are neither interchangeable with parts from other manufacturers nor upgradeable. If broken or damaged, they must be substituted with an exact replacement part. Those users uneducated in the relevant fields are those the most affected by incompatibilities, especially if they attempt to connect their laptops with incompatible hardware or power adapters.

Intel, Asus, Compal, Quanta and other laptop manufacturers have created the Common Building Block standard for laptop parts to address some of the inefficiencies caused by the lack of standards.

[edit] Advantages

Laptop computers are portable and can be used in many locations. Shown here is former Mexican president Vicente Fox.

Portability is usually the first feature mentioned in any comparison of laptops versus desktop PCs.[36] Portability means that a laptop can be used in many places—not only at home and at the office, but also during commuting and flights, in coffee shops, in lecture halls and libraries, at clients' location or at a meeting room, etc. The portability feature offers several distinct advantages:

* Getting more work done – Using a laptop in places where a desktop PC can't be used, and at times that would otherwise be wasted. For example, an office worker managing their e-mails during an hour-long commute by train, or a student doing his/her homework at the university coffee shop during a break between lectures.[37]

* Immediacy – Carrying a laptop means having instant access to various information, personal and work files. Immediacy allows better collaboration between coworkers or students, as a laptop can be flipped open to present a problem or a solution anytime, anywhere.

* Up-to-date information – If a person has more than one desktop PC, a problem of synchronization arises: changes made on one computer are not automatically propagated to the others. There are ways to resolve this problem, including physical transfer of updated files (using a USB flash memory stick or CDRs) or using synchronization software over the Internet. However, using a single laptop at both locations avoids the problem entirely, as the files exist in a single location and are always up-to-date.

* Connectivity – A proliferation of Wi-Fi wireless networks and cellular broadband data services (HSDPA, EVDO and others) combined with a near-ubiquitous support by laptops[38] means that a laptop can have easy Internet and local network connectivity while remaining mobile. Wi-Fi networks and laptop programs are especially widespread at university campuses.[39]

Other advantages of laptops include:

* Size – Laptops are smaller than standard PCs. This is beneficial when space is at a premium, for example in small apartments and student dorms. When not in use, a laptop can be closed and put away.

* Ease of Access - Most laptops have doors on the underside that allow the user to access the memory, hard drive and other components, by simply flipping the laptop to access the doors. For desktops the user must usually access the backside of the computer, which is harder if it's in an area with little space.

* Low power consumption – Laptops are several times more power-efficient than desktops. A typical laptop uses 20-90 W, compared to 100-800 W for desktops. This could be particularly beneficial for businesses (which run hundreds of personal computers, multiplying the potential savings) and homes where there is a computer running 24/7 (such as a home media server, print server, etc.)

* Quiet – Laptops are often quieter than desktops, due both to the components (quieter, slower 2.5-inch hard drives) and to less heat production leading to use of fewer and slower cooling fans.

* Battery – a charged laptop can run several hours in case of a power outage and is not affected by short power interruptions and blackouts. A desktop PC needs a UPS to handle short interruptions, blackouts and spikes; achieving on-battery time of more than 20–30 minutes for a desktop PC requires a large and expensive UPS.[40]

* All-in-One - designed to be portable, laptops have everything integrated in to the chassis. For desktops (excluding all-in-ones) this is divided into the desktop, keyboard, mouse, display, and optional peripherals such as speakers, and a webcam. This leads to lots of wiring. It can also lead to massive power consumption.

* Extras - in comparison to low-end desktops, even low-end laptops include features such as integrated Wi-Fi, and Express Card slot, and a memory card reader.

[edit] Disadvantages

Compared to desktop PCs, laptops have disadvantages in the following fields:

[edit] Performance

Whilst the performance of mainstream desktops and laptops is comparable, laptops are significantly more expensive than desktop PCs at the same or even lower performance level.[41] The upper limits of performance of laptops are a little bit lower, and "bleeding-edge" features usually appear first in desktops and only then, as the underlying technology matures, are adapted to laptops.

However, for Internet browsing and typical office applications, where the computer spends the majority of its time waiting for the next user input, even netbook-class laptops are generally fast enough.[42] Most higher-end laptops are sufficiently powerful for high-resolution movie playback, 3D gaming and video editing and encoding. However, laptops are disadvantaged when dealing with database, math, engineering, financial software, etc.

Some manufacturers work around this performance problem by using desktop CPUs for laptops.[43]

[edit] Upgradeability

Upgradeability of laptops is very limited compared to desktops, which are thoroughly standardized. In general, hard drives and memory can be upgraded easily. Optical drives and internal expansion cards may be upgraded if they follow an industry standard, but all other internal components, including the CPU, motherboard and graphics, are not intended to be upgradeable.

The reasons for limited upgradeability are both technical and economic. There is no industry-wide standard form factor for laptops; each major laptop manufacturer pursues its own proprietary design and construction, with the result that laptops are difficult to upgrade and have high repair costs. With few exceptions, laptop components can rarely be swapped between laptops of competing manufacturers, or even between laptops from the different product-lines of the same manufacturer.

Some upgrades can be performed by adding external devices, either USB or in expansion card format such a PC Card: sound cards, network adapters, hard and optical drives, and numerous other peripherals are available, but these upgrades usually impair the laptop's portability, because they add cables and boxes to the setup and often have to be disconnected and reconnected when the laptop is moved.

[edit] Ergonomics and health

Laptop coaster preventing heating of lap and improving laptop airflow.

Because of their small and flat keyboard and trackpad pointing devices, prolonged use of laptops can cause repetitive strain injury.[44] Usage of separate, external ergonomic keyboards and pointing devices is recommended to prevent injury when working for long periods of time; they can be connected to a laptop easily by USB or via a docking station. Some health standards require ergonomic keyboards at workplaces.

The integrated screen often causes users to hunch over for a better view, which can cause neck or spinal injuries. A larger and higher-quality external screen can be connected to almost any laptop to alleviate that and to provide additional "screen estate" for more productive work.

A study by State University of New York researchers found that heat generated from laptops can raise the temperature of the scrotum when balancing the computer on one's lap, potentially putting sperm count at risk. The study, which included roughly two dozen men aged 21 to 35, found that the sitting position required to balance a laptop can raise scrotum temperature by as much as 2.1 °C (3.78 °F). Heat from the laptop itself can raise the temperature by another 0.7 °C (1.26 °F), bringing the potential total increase to 2.8 °C (5.04 °F). However, further research is needed to determine whether this directly affects sterility in men.[45]

A common practical solution to this problem is to place the laptop on a table or desk. Another solution is to obtain a cooling unit for the laptop, these units are usually USB powered and consist of a hard thin plastic case housing 1, 2 or 3 cooling fans (with the entire assembly designed to sit under the laptop in question) which results in the laptop remaining cool to the touch, and greatly reduces laptop heat buildup.

Heat from using a laptop on the lap can also cause skin discoloration on the thighs.[46]

[edit] Durability

A clogged heatsink on a 2.5 year old laptop.

Due to their portability, laptops are subject to more wear and physical damage than desktops. Components such as screen hinges, latches, power jacks and power cords deteriorate gradually due to ordinary use. A liquid spill onto the keyboard, a rather minor mishap with a desktop system, can damage the internals of a laptop and result in a costly repair. One study found that a laptop is 3 times more likely to break during the first year of use than a desktop.[47]

Original external components are expensive, and usually proprietary and non-interchangeble; other parts are inexpensive—a power jack can cost a few dollars—but their replacement may require extensive disassembly and reassembly of the laptop by a technician. Other inexpensive but fragile parts often cannot be purchased separate from larger more expensive components.[48] The repair costs of a failed motherboard or LCD panel may exceed the value of a used laptop.

Laptops rely on extremely compact cooling systems involving a fan and heat sink that can fail due to eventual clogging by accumulated airborne dust and debris. Most laptops do not have any sort of removable dust collection filter over the air intake for these cooling systems, resulting in a system that gradually runs hotter and louder as the years pass. Eventually the laptop starts to overheat even at idle load levels. This dust is usually stuck inside where casual cleaning and vacuuming cannot remove it. Instead, a complete disassembly is needed to clean the laptop.

Battery life of laptops is limited; the capacity drops with time, necessitating an eventual replacement after a few years. The battery is often easily replaceable, and one may replace it on purpose with a higher end model to achieve better battery life.

[edit] Security

Being valuable, common and portable, laptops are prized targets for theft. The cost of the stolen business or personal data and of the resulting problems (identity theft, credit card fraud, breach of privacy laws) can be many times the value of the stolen laptop itself. Therefore, both physical protection of laptops and the safeguarding of data contained on them are of the highest importance.

Most laptops have a Kensington security slot which is used to tether the computer to a desk or other immovable object with a security cable and lock. In addition to this, modern operating systems and third-party software offer disk encryption functionality that renders the data on the laptop's hard drive unreadable without a key or a passphrase.

Some laptops also now have additional security elements added by the consumer, including eye recognition software and fingerprint scanning components.





Wednesday, 10 March 2010

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Metastable Nanosized Diamond Formation from Fluid Systems S. K. Simakova, aGeological Department, St.Petersburg University, 7/9 Universitetskaya Nab., St.Petersburg, 199034, Russia

The model of nanosized diamond particles formation at metastable P-T parameters from fluid is presented. It explains the specific of CVD diamond synthesis gases mixtures and hydrothermal growth of diamond at low P-T parameters as well as it explains the geneses of metamorphic and magmatic nano- and microdiamond in the shallow depth Earth rocks and the genesis of interstellar nanodiamond formations in the space.

The optimal gases system compositions for metastable diamond formations have been long debated in many publications during the long period. Badziag et al.1 came to the conclusion that nanometer-sized diamonds could be more stable than graphite when formed from hydrocarbons with a H/C ratio of more than 0.24. Simakov2 has shown that the addition of oxygen to the hydrocarbon gases can stabilize the diamond nucleus formation in the P-T field of graphite stability. The question of whether diamond could be grown under hydrothermal conditions mimicking those under which it is formed in the Earth has been also long debated3,4. Roy et al.5 have made the detailed study of the hydrothermal growth of diamond in the C-H-O and C-H-O-halogen systems. Shimansky et al.6 have claimed hydrothermal growth of diamond but no details were given on the composition of the liquid and the characterization of the phases. Zhao et al.7 provided the diamond hydrothermal synthesis from the mixture of the glassy carbon, powdered nickel, diamond seeds and water at 800o C and 1.4 kbar. From another hand, Bachmann et al.8 have analysed gaseous compositions of the different 78 CVD diamond syntheses and shown that their compositions lie in the corridor extended range from H to CO compositions of the C-O-H system. The triangularly shaped “diamond domain” is adjusted along the CO line of the diagram and is limited by the lines XCO2 0.57 on its carbon-rich side and XCO2 0.45 on its oxygen-rich side (see Fig. 1 in ref. 8). The main part of the synthesis compositions lies in the middle part of the domain between methane and acetylene lines meanwhile only the lesser part corresponds to hydrogen.

For diamond, it has been argued, that crystallization under P-T conditions, where diamond is actually thermodynamically unstable with respect to graphite, is possible due to kinetic factors 9,10. Nanosize diamond particles have energetic preference upon graphitic particles of the same size and could be more stable at low P-T parameters (ref.1)11-13. Fedoseev et al.14 have shown that critical radii of graphite and diamond nuclei depends upon the surface energy (s), atomic volume of carbon (V) and chemical potential of the resaturation (Dm):

rg/rd = Vgsg Dmd / Vdsd Dmg (1)

s of nanosized diamond (d) and graphite (g) particles depends upon temperature and size of the particles15. From sg/sd relation given in16 and from (ref.12) it follows that for nanoparticles Vgsg/Vdsd 1. Than rg/rd ratio could be expressed as:

rg/rd = Dmd / Dmg (2)

On the other hand the chemical potentials of the resaturation for diamond and graphite could be expressed as follows:

Dmg =RTln(Pi/Pig) (3)

Dmd =RTln(Pi/Pid) (4)

where Pi and Pig,d are the real and equilibrium pressures of carbonaceous gases

As it follows from equations (2-4), (rg/rd) depends on the ratio between real and calculated equilibrium pressures of carbonaceous gases. Within the range of graphite stability Pig <>d, which corresponds to preferable graphite formation from fluid phase. The condition of preferable diamond formation corresponds to Pig > Pid. The difference between Dmg and Dmd depends upon the difference of Pi/Pig and Pi/Pid , and at lower Picar it tends to zero, which corresponds to optimal condition of diamond formation from gaseous mixture within the range of graphite stability.

In the hydrocarbon-hydrogen mixture the gas-solid reaction of hydrocarbon destruction could be proposed for carbon formation in a fluid:

CH4 ® C + 2H2 (I)

At high temperatures equilibrated pressure of hydrogen would be greater than equilibrated pressure of methane and in vacuum PCH4(d) tends to PCH4(g) (Fig.1,A). The predomination of hydrogen under hydrocarbon in the gaseous mixture has also suppressed the growth rate of graphite more than it suppressed the growth rate of diamond (ref.10). As a result, it could stabilize the diamond growth at these conditions. Based on this effect, Deryagin and Fedoseev (ref.9) have grown diamond on the diamond seeds at vacuum conditions.

Subsequent work has shown that the addition of oxygen to the hydrocarbon gases can stabilize the diamond nucleus formation in the P-T range of graphite stability (ref.2). This conclusion coincides with the established fact that diamond is more stable in the oxygen environment than graphite, because oxygen reduces graphite to a greater degree than diamond17. Calculations done for the C-O-H system show that PCH4(car) is very low within the ranges of the system, close to the upper limit of carbon stability by oxygen (CCO buffer)18. Within the ranges at lower pressure and temperature, PCH4(g) PCH4(d), which corresponds to diamond nucleus stabilization.

The presented model explains the extended Bachmann’s “diamond domain” along the CO line from H to CO compositions in the C-O-H system (ref. 8). The fluid calculations performed at 1000o C and 10-3 bar within the wide range of oxygen fugacity show that the diamond stability range corresponds in more degree to CO composition and in less degree to H2 composition of the gases mixture (Fig. 1,A).

From the calculations it follows that this model provides a common basis for low-pressure diamond CVD methods. It comprises and connects data for more than 30 years of diamond CVD. By means of this model, special relations between very different source gasses and gas mixtures become clear. On the other hand, the model explains the possibility of metastable hydrothermal growth of the diamond too (Fig. 1, C). Our experiments at 500°C and total pressure of nearly 1000 bar from water liquid of organic matter proved the possibility of nanodiamond formation from C-O-H fluids at low temperatures and pressures without seeds 19. The determined relations may help to develop new models of the surface processes and growth species needed for diamond deposition.

It is known that the bulk of Earth diamonds is formed due to the deep upper mantle rocks - kimberlites formed at P and T corresponding to diamond thermodynamic stability. Meanwhile for the last 40 years micro- and nanodiamonds have also been found in shallow metamorphic earth rocks formed at P-T parameters corresponding to graphite thermodynamic stability 20-22 as well as in the basalts 23,24. The highest grade is observed in hydrothermal metasomatic zones of Kokchetave metamorphic massive situated in Northern Kazakhstan 25. The fluid calculations performed at P-T parameters corresponded to Hawaiian basalt formation show that the diamond stability range here corresponds to CO2 and H2O compositions of the fluid (Fig. 1,B). It explains the relationship of Hawaiian nanodiamonds with carbon dioxide fluids (ref.24). The calculations performed at lower P-T parameters corresponded to hydrothermal metasomatic zones of Kokchetave metamorphic massive formation show that the diamond stability range also corresponds to CO2 and H2O compositions of the fluid (Fig. 1,C). It explains the relationship of the Kokchetave diamonds with water and carbon dioxide26.

The origin of diamonds in the interstellar space has been a topic of intense discussion since the discovery of presolar nanodiamonds in chondrites 27. Meteoritic nanodiamonds provide information on the nucleosynthesis of evolved stars and the evolution of the astrophysical environment, which formed the solar system. Sellgren 28 identified the relationship between the interstellar diamond and water ice. Nakano et al.29 related interstellar diamond formation with organic matter. Based on these relationships Kouch et al.30 identified new formation routes of diamond in the interstellar clouds and parent bodies of carbonaceous chondrites during laboratory experiments. It’s the ice mixture of H2O, CO, NH3 and CH 4 (4 : 2 : 2 : 1). The questions of when and how does nanodiamonds originate in the Cosmos remain open, although comparative microstructural analysis of nanodiamonds extracted from meteorites, indicates that the majority of cosmic nanodiamonds are formed by low-pressure vapor condensation31. The fluid calculations performed at 250o C and 10-3 bar show that the diamond stability range here corresponds to CO2 and H2O compositions of the fluid (Fig. 1,D). It explains the relationship of interstellar diamonds with water (ref. 28).

The presented in the paper model explains the specificity of the CVD diamond synthesis gas compositions and the hydrothermal growth of diamond at low P-T parameters as well as the geneses of metamorphic and magmatic nano- and microdiamond in the shallow depth Earth rocks and of interstellar nanodiamonds in the space at P-T parameters corresponding to graphite stability. Nanosized diamond particles could be formed from carbon-bearing fluids at low temperatures and pressures without seeds in the range of the upper limit of carbon stability by oxygen.

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